The dynamic duo known as Aviida, joined coach Delta Goodrem as part of season four's second episode, where they wooed the judges with a rendition of Adele's One and Only.
Aviida, which has been busy gigging around Perth, made the audition announcement on social media site Facebook, encouraging supporters to tune in last night.
"Thank you for all the love today," the post said. "This is our exciting time and we are blessed from above to be able to share this journey together as husband and wife, best friends, grandparents, parents, and partners in life.
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Parore first rose to fame during the show's first season, where she battled it out against eventual winner Karise Eden.
Aviida will now head into the battle rounds to compete against fellow artists to advance.
The season premiere featured host Darren McMullen joined by Sonia Kruger while new coaches Jessie J and Benji Madden joined seasoned coaches Joel Madden, Ricky Martin and Delta Goodrem.
The winner of The Voice 2015 will receive a recording contract with Universal Music Australia, $100,000 cash and a Ford Kuga Titanium.