A white prime mover towing two yellow cylindrical tankers failed to negotiate a lefthand bend and entered the centre median reserve immediately prior to the Nambeelup Brook Bridge.
It continued between the north and southbound lane carriageway, entering a deep culvert and coming to rest directly below the south bound carriageway.
The 42-year-old male driver died shortly after at the scene.
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READ NOWMajor Crash investigators are seeking witnesses who may have seen the vehicle driving in the Martin area before the crash.